300773-22-2Relevant academic research and scientific papers
The co-ordination chemistry of 2-(diphenyIphosphinoamino)pyridine 1
Aucott, Stephen M.,Slawin, Alexandra M. Z.,Derek Woollins
, p. 2559 - 2575 (2007/10/03)
2-(Diphenylphosphinoamino)pyridine, dppap [Ph2PNHpy], and over 40 illustrative examples of its complexes have been prepared. Monodentate, bidentate and bridging co-ordination of the neutral (and bidentate deprotonated ligand) has been demonstrated in a range of palladium, platinum and gold complexes. Ten demonstrative examples have been characterised by single crystal X-ray diffraction. Ph2PNHpy exists as hydrogen-bonded dimer pairs; cis[PtCl(Ph2PNHpy-P,Ar){Ph2PNHpy-P}]Cl packs in hydrogen-bonded infinite chains; cis-[PtCPh2PNpy-.P.A2] and cis-[Pd(Ph2PNpy-P,N)2] are isomorphous. The structures of cis-[Pd(Ph2PNHpy-P,N)2][BF4]2, [AuCl(Ph2PNHpy-.P)], [Pt(C8H12OMe)(Ph2PNpy-P,N)]-H2O illustrating hydrogen-bonding, cis-[PtCl(Ph2PNHpy-P,N)(PMe3)]Cl, cis[PtCl(Ph2PNpy-P,N(PMe3)] and cis-[PtCl(Ph2PNHpy-P,N)(P(OPh)3)]Cl are also reported. The Royal Society of Chemistry 2000.
