300830-72-2Relevant academic research and scientific papers
Structural correlations for nucleophilic addition to the C=O group: The solvation angle
Davies, John E.,Kirby, Anthony J.,Komarov, Igor V.
, p. 1222 - 1233 (2007/10/03)
We report some new observations in Buergi-Dunitz territory - structure-structure correlations for the addition of N nucleophiles to the C=O group. The amino aldehyde 1 exists predominantly in polar solvents, and exclusively in the crystal, as the carbonyl
