301645-93-2

Upstream product

• 106-95-6 allyl bromide 
• 185446-93-9 (2R,3S,4R,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-methylsulfanyl-tetrahydro-pyran-3-ol 
• 129163-10-6 methyl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 85993-78-8 2-O-acetyl-3,4,6-tri-O-benzyl-D-mannopyranosyl chloride 

Downstream Products

• 112330-11-7 (3,4,6-tri-O-benzyI-β-D-mannopyranosyl)-(1→6)-1,2,3,4-di-O-isoprpopylidene-α-D-galactopyranoside 
• 244282-24-4 cyclohexyl 3,4,6-tri-O-benzyl-β-D-mannopyranoside 
• 455929-01-8 (3aR,5R,5aS,8aS,8bR)-5-[1-((2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-methylsulfanyl-tetrahydro-pyran-3-yloxy)-2-iodo-propoxymethyl]-2,2,7,7-tetramethyl-tetrahydro-bis[1,3]dioxolo[4,5-b;4',5'-d]pyran 
• 455929-15-4 (2R,3R,4S,5S,6R)-3,4-Bis-benzyloxy-2-benzyloxymethyl-5-(1-cyclohexyloxy-2-iodo-propoxy)-6-methylsulfanyl-tetrahydro-pyran 
• 301645-94-3 methyl 2-O-(prop-1-enyl)-3,4,6-tri-O-benzyl-1-thio-α-D-mannopyranoside 

Relevant academic research and scientific papers

Stereoselective 1,2-cis glycosylation of 2-O-Allyl protected thioglycosides

The technique of intramolecular aglycon delivery (IAD), whereby a glycosyl acceptor is temporarily appended to a hydroxyl group of a glycosyl donor is an attractive method that can allow the synthesis of 1,2-cis glycosides in an entirely stereoselective f

Stereoselective cis glycosylation of 2-O-allyl protected glycosyl donors by intramolecular aglycon delivery (IAD)

2-O-Allyl protected glycosyl donors may be glycosylated stereoselectively via a three step sequence involving double bond isomerization, N-iodosuccinimide mediated tethering to a glycosyl acceptor and subsequent intramolecular glycosylation (intramolecula