30166-31-5Relevant academic research and scientific papers
α,β-Unsaturated Carboxylic Acid Derivatives. Part 18. Syntheses of Geometric Isomers of 3,6-Dibenzylidene- and 3-p-Anisylidene-6-benzylidene-2,5-piperazinediones
Shin, Chung-gi,Hayakawa, Masato,Kato, Haruo,Mikami, Kazutoshi,Yoshimura, Juji
, p. 419 - 421 (2007/10/02)
Naturally occuring 3,6-dibenzylidene- and 3-p-anisylidene-6-benzylidene-2,5-piperazinediones and their geometric isomers were synthesized by the condensation of 1-acetyl or 1,4-diacetyl derivative of (E)- and (Z)-benzylidene- or p-anisylidene-2,5-piperazinediones with an appropriate aldehyde.The configuration of these compounds were assigned on the basis of the spectroscopic analyses, and those of natural products were determined to be (3Z,6Z).
