301844-20-2Relevant academic research and scientific papers
Conformational memory in enantioselective radical reductions and a new radical clock reaction
Buckmelter, Alexandre J.,Kim, Angie I.,Rychnovsky, Scott D.
, p. 9386 - 9390 (2007/10/03)
The radical decarboxylation of acid 1 led to tetrahydropyran 3 with significant optical activity. This transfer of chirality is an example of a conformational memory effect and derives from the slow ring inversion of the atropisomer 2 and its enantiomer 2
