3019-87-2

Basic information

• Product Name: Ethanone, 1-(3-hydroxyphenyl)-, sodium salt
• CAS NO: 3019-87-2
• Molecular Formula: C8H8O2.Na
• Molecular Weight: 158.132
• Mol File: 3019-87-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-(3-hydroxyphenyl)-, sodium salt(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(3-hydroxyphenyl)-, sodium salt(3019-87-2)
• EPA Substance Registry System: Ethanone, 1-(3-hydroxyphenyl)-, sodium salt(3019-87-2)

Safety Data

• Hazardous Substances Data: 3019-87-2(Hazardous Substances Data)

Upstream product

• 121-71-1 3-Hydroxyacetophenone 
• 1268380-12-6 C₁₅H₁₂O₄ 

Downstream Products

• 32852-92-9 3'-phenoxyacetophenone 
• 63990-82-9 1-[3-(2-hydroxy-3-morpholin-4-yl-propoxy)-phenyl]-ethanone 
• 87343-72-4 C₁₇H₁₆N₂O₄ 
• 87343-71-3 C₁₆H₁₄N₂O₄ 
• 83537-24-0 ethyl trans-3-(3-phenoxybenzoyl)glycidate 
• 52955-87-0 2-bromo-1-(3-phenoxyphenyl)ethanone 
• 42865-03-2 1-[3-(2,3-epoxy-propoxy)-phenyl]-ethanone 
• 52177-72-7 C₉H₇ClO₃ 

Relevant articles and documents

Kinetics and mechanism of alkaline hydrolysis of Y-substituted phenyl phenyl carbonates

Second-order rate constants (kOH-) have been measured spectrophotometrically for alkaline hydrolysis of Y-substituted phenyl phenyl carbonates (2a-j) and compared with the kOH- values reported previously for the corresponding reactions of Y-substituted phenyl benzoates (1a-j). Carbonates 2a-j are 8 ～ 16 times more reactive than benzoates 1a-j. The Hammett plots correlated with σ- and σo constants exhibit many scattered points, while the Yukawa-Tsuno plot results in excellent linear correlation with ρ = 1.21 and r = 0.33. Thus, the reaction has been concluded to proceed through a concerted mechanism in which expulsion of the leaving group is advanced only a little. However, one cannot exclude a possibility that the current reaction proceeds through a forced concerted mechanism with a highly unstable intermediate.