303030-16-2

Upstream product

• 112-16-3 n-dodecanoyl chloride 
• 303030-15-1 4-amino-4'''-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-[1,4';1',1'';4'',1''']quaterphenyl-3,2''-dicarboxylic acid dimethyl ester 
• 5467-74-3 4-Bromophenylboronic acid 
• 77317-55-6 methyl 2-amino-5-iodobenzoate 
• 303030-10-6 4-amino-4'-bromo-biphenyl-3-carboxylic acid methyl ester 
• 303030-11-7 4'-bromo-4-iodo-biphenyl-3-carboxylic acid methyl ester 
• 303030-12-8 4-amino-4'-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-biphenyl-3-carboxylic acid methyl ester 
• 303030-13-9 4-amino-4'''-bromo-[1,4';1',1'';4'',1''']quaterphenyl-3,2''-dicarboxylic acid dimethyl ester 

Relevant academic research and scientific papers

Convenient iterative synthesis of an octameric tetracarboxylate-functionalized oligophenylene rod with divergent end groups

(matrix presented) Oligo(p-phenylene) rigid rod 10 is synthesized via a functional group-tolerant molecular doubling approach. Preparative chromatographic methods, protecting groups, boronic acid isolations, and Grignard or organolithium reagents are not used. The convenient synthesis of well-defined, polar-functionalized oligophenylene rigid rods could afford ready access to a variety of useful electronic organic materials.