303123-76-4

Upstream product

• 5344-90-1 2-Aminobenzyl alcohol 
• 87696-33-1 (S)-2-(O-tert-butyldiphenylsilyloxy)propanal 
• 303123-78-6 (1''S,2'R)-1-[2'-(1''-tert-butyldiphenylsiloxyethyl)-4'H-benzo[d][1',3']oxazin-1'-yl]-propan-1-one 
• 303123-77-5 (1''S,2'S)-1-[2'-(1''-tert-butyldiphenylsiloxyethyl)-4'H-benzo[d][1',3']oxazin-1'-yl]-propan-1-one 
• 303123-83-3 (1''S,2S,2'R)-1-[2'-(1''-tert-butyldiphenylsiloxyethyl)-4'H-benzo[d][1',3']oxazin-1'-yl]-2-methylpent-4-en-1-one 
• 303123-79-7 (1''S,2R,2'S)-1-[2'-(1''-tert-butyldiphenylsiloxyethyl)-4'H-benzo[d][1',3']oxazin-1'-yl]-2-methylpent-4-en-1-one 

Downstream Products

• 303123-83-3 (1''S,2S,2'R)-1-[2'-(1''-tert-butyldiphenylsiloxyethyl)-4'H-benzo[d][1',3']oxazin-1'-yl]-2-methylpent-4-en-1-one 
• 303123-79-7 (1''S,2R,2'S)-1-[2'-(1''-tert-butyldiphenylsiloxyethyl)-4'H-benzo[d][1',3']oxazin-1'-yl]-2-methylpent-4-en-1-one 
• 303123-78-6 (1''S,2'R)-1-[2'-(1''-tert-butyldiphenylsiloxyethyl)-4'H-benzo[d][1',3']oxazin-1'-yl]-propan-1-one 
• 303123-77-5 (1''S,2'S)-1-[2'-(1''-tert-butyldiphenylsiloxyethyl)-4'H-benzo[d][1',3']oxazin-1'-yl]-propan-1-one 

Relevant academic research and scientific papers

Chiral Acetals as Stereoinductors: Diastereoface Selective Alkylation of Dihydrobenzoxazine-Derived Amide Enolates

Novel dihydrobenzoxazine-derived acetals of type 3 have been developed for asymmetric C-alkylations of propionyl amide enolates. High stereoselectivities are obtained for amides 15 and 22 which are rationalized in terms of intramolecular metal chelate formation.