303197-59-3Relevant academic research and scientific papers
Synthesis and characterization of heterodinuclear thiolate complexes containing the Pd(η3-allyl)+ moiety. Crystal structure of [(dppe)Pd(μ-SC6H4Me-p)2Pd(η3-C3H5)][ClO4]
Ruiz, José,Giner, José,Rodríguez, Venancio,López, Gregorio,Casabó, Jaume,Molins, Elies,Miravitlles, Carles
, p. 1627 - 1631 (2008/10/08)
Heterodinuclear complexes of the types [(dppe)M(μ-SR)2Pd(η3-allyl)][ClO4] (M = Pd or Pt) and [(dppe)Pt(μ-SC2H4S)Pd(η3-allyl)][ClO4] [dppe = 1,2-bis(diphenylphosphino)ethane; allyl = C3H5 or C4H7] have been obtained by reaction of the corresponding cis-dithiolato complexes, [M(SR)2 (dppe)] or [Pt(SC2H4S)(dppe)], and [Pd(η3-allyl)(PhCN)2][ClO4]. The identity of these complexes has been established by NMR (1H and 31P) spectroscopy. The crystal structure of [(dppe)Pd(μ-SC6H4Me-p)2Pd(η3-C3H5)][ClO4] has been determined by single-crystal X-ray methods. The p-tolyl groups on the sulfur atoms adopt a syn conformation with respect to the central Pd-S2-Pd core. (C) 2000 Elsevier Science Ltd.
