30369-04-1Relevant articles and documents
SYNTHESIS AND PROPERTIES OF DERIVATIVES OF sym-TRIAZINES. 11. SYNTHESIS OF 2-AMINO-sym-TRIAZINES CONTAINING ALKYL RADICALS
Kelarev, V. I.,Karakhanov, R. A.,Polivin, Yu. N.,Kuatbekov, A. M.,Remizov, A. S.,Mikaya, A. I.
, p. 1087 - 1092 (1993)
2-Amino-4,6-dialkyl-sym-triazenes were synthesized by the condensation of aliphatic nitriles with guanidine. 2-Amino-4-alkyl-6-substituted sym-triazines were prepared by the reaction of N-acylguanidines with nitriles or imino esters.Aminotriazines of this type are also formed in the condensation of N-imidoylguanidines with esters.
SYNTHESIS AND PROPERTIES OF SYMM-TRIAZINES. 3. REACTIONS OF 2-ALKYL-4,6-BISTRICHLOROMETHYL-symm-TRIAZINES CONTAINING HIGHER ALKYL GROUPS WITH AMMONIA AND ALIPHATIC AMINES
Kelarev, V. I.,Dibi, Ammar,Lunin, A. F.
, p. 1284 - 1289 (2007/10/02)
The reaction of 2-alkyl-4,6-bistrichlormethyl-symm-triazines containing higher alkyl groups with ammonia or aliphatic amines results, depending on the reaction conditions, in the replacement of one or both trichloromethyl groups.On heating these symm-triazines with aqueous ammonia or diethylamine, 2-oxo-4-amino-6-alkyl-1(3)H-symm-triazines are obtained.
