30384-72-6Relevant academic research and scientific papers
Microwave-assisted one step high-throughput synthesis of benzimidazoles
Lin, Shou-Yuan,Isome, Yuko,Stewart, Ethan,Liu, Ji-Feng,Yohannes, Daniel,Yu, Libing
, p. 2883 - 2886 (2006)
One-pot synthesis of benzimidazoles from diamines and carboxylic acids was developed under microwave irradiation condition, which provided a practical and efficient method for high-throughput synthesis of this important class of heterocyclic compounds.
Synthesis and fluorescent properties of 2-(1H-benzimidazol-2-yl)-phenol derivatives
Ouyang, Jie,Ouyang, Chenguang,Fujii, Yuki,Nakano, Yoshiharu,Shoda, Takuji,Nagano, Tetsuo
, p. 359 - 365 (2007/10/03)
A high yield one pot synthesis of 2-(2-hydroxyaryl)-1H-benzimidazole derivatives by 2-hydroxy aromatic aldehydes with aromatic 1,2-diamines in the presence of manganese(III) acetate at room temperature was developed. Nine fluorescencers 2-(2-hydroxyaryl)-1H-benzimidazoles with substituent(s) X (X = H, CH3, CH3O, Cl) and two fluorescencers 2-(2-hydroxyaryl)-1H-naphth[2,3-d]imidazoles with substituent of H or Cl were prepared in 38-87% yield and the ultraviolet absorption and fluorescent spectra of the eleven compounds synthesized were measured in methanol. The fluorescent characteristics of the 2-(2-hydroxyaryl)benzimidazole derivatives prepared were investigated on the basis of excited-state intramolecular proton transfer mechanism, Stokes' shift, quantum yield, and the relationship between fluorescent intensity and the substituents were derived.
