30393-06-7Relevant academic research and scientific papers
STEREOSELECTIVITIES OF BENZONITRILE OXIDE CYCLOADDITIONS TO CIS DISUBSTITUTED CYCLOPENTENES AND DIHYDROFURANS
Caramella, P.,Albini, Marinone F.,Vitali, D.,Rondan, Nelson G.,Wu, Yun-Dong,et al.
, p. 1875 - 1878 (2007/10/02)
Benzonitrile oxide cycloadds preferentially anti to the substituents of cis-3,5-di-X-cyclopentenes, where X= OMe, OAc, OCOPh, Br, Cl, and OH.Higher stereoselectivities are found for cis-2,5-di-X-2,5-dihydrofurans.The origins of these selectivities, and contrasts with acyclic and cyclobutene analogs, are described.
