30457-93-3

Upstream product

• 113616-19-6 C₇H₁₁BrOZn 

Downstream Products

• 791123-32-5 (R)-1-[(R)-2-(2-Methyl-allyl)-oxiranyl]-prop-2-en-1-ol 
• 791123-33-6 (S)-1-[(R)-2-(2-Methyl-allyl)-oxiranyl]-prop-2-en-1-ol 
• 1015098-65-3 4-methyl-2-methylenepent-4-enyl 3-(3-tolyl)prop-2-ynyl ether 
• 1015098-71-1 N-[(1-naphthyl)prop-2-ynyl]-N-tosyl-4-methyl-2-methylenepent-4-en-1-amine 
• 1015098-66-4 4-methyl-2-methylenepent-4-enyl 3-(2-tolyl)prop-2-ynyl ether 
• 1015098-64-2 4-methyl-2-methylenepent-4-enyl 3-(4-tolyl)prop-2-ynyl ether 
• 1439440-17-1 (R)-7-(4-methoxybenzyl)-8a-methyl-2-methylene-2,3,8,8a-tetrahydroindolizin-5(1H)-one 

Relevant academic research and scientific papers

OXYGEN AND NITROGEN HETEROCYCLES BY INTRAMOLECULAR MAGNESIUM- AND ZINC-ENE REACTIONS; METHYLENECYCLOPENTANES BY Pd(0)-CATALYSED ISOMERIZATION OF 5-(BROMOZINCMETHYL)-3-METHYLENEOXACYCLOALKANES

2-(Alkenyloxymethyl)-2-propenylzinc bromides 2a-e and 2-(allylmethylaminomethyl)-2-propenylzinc (or magnesium) halides 2g rearrange thermally to 5-(1-bromozincalkyl)-3-methyleneoxacycloalkanes 1a-e and 5-(bromozinc(or chloromagnesium)methyl)-3-methylene-N-methylpiperidine 1g; some of the former can be isomerized by Pd(PPh3)4 to methylenecyclopentanes 3.