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6-amino-5-cyano-2-methyl-4-(4-trifluoromethylphenyl)-4H-pyran-3-carboxylic acid ethyl ester is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

304878-44-2

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304878-44-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 304878-44-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,0,4,8,7 and 8 respectively; the second part has 2 digits, 4 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 304878-44:
(8*3)+(7*0)+(6*4)+(5*8)+(4*7)+(3*8)+(2*4)+(1*4)=152
152 % 10 = 2
So 304878-44-2 is a valid CAS Registry Number.

304878-44-2Downstream Products

304878-44-2Relevant articles and documents

Silica-bonded N-propylpiperazine sodium n-propionate as recyclable catalyst for synthesis of 4H-pyran derivatives

Niknam, Khodabakhsh,Borazjani, Nassim,Rashidian, Reza,Jamali, Abbas

, p. 2245 - 2254 (2013)

Silica-bonded N-propylpiperazine sodium n-propionate (SBPPSP) was found to act as an efficient solid base for the preparation of a series of 4H-benzo[b]pyran derivatives. SBPPSP was used as a recyclable heterogeneous solid base catalyst for the synthesis

Novel MgO-SnO2 solid superbase as a high-efficiency catalyst for one-pot solvent-free synthesis of polyfunctionalized 4H-pyran derivatives

Zhang, Shu-Guo,Yin, Shuang-Feng,Wei, Yu-Dan,Luo, Sheng-Lian,Au, Chak-Tong

, p. 608 - 614 (2012)

We report for the first time the hydrothermal synthesis of MgO-SnO 2 solid superbase using P123 as template. The basicity of the materials was determined by two approaches of Hammett indicators method and temperature- programmed desorption using CO2 as adsorbate (CO 2-TPD). It was found that Mg/Sn molar ratio has an effect on MgO-SnO2 basicity, and superbasicity was observed only at Mg/Sn molar ratio of 1. With variation of Mg/Sn molar ratio, superbase strength (H-) was in the 26.5-33.0 range, showing superbasic value up to 0.939 mmol/g. The structure and texture of the as-prepared materials were studied by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), and N2 physioadsorption methods. We detected particles of spherical morphology having diameter of ca. 150 nm. N2 adsorption- desorption results suggested that the materials are of mesoporous structure, having specific surface area of 115.2 m2/g and average pore diameter of 6 nm. The superbase was found to exhibit excellent catalytic activity towards the one-pot synthesis of polyfunctionalized 4Hpyrans through the condensation of aldehydes, malononitrile, and an active methylene compound. Its excellent catalytic efficiency is related to its superbasicity of the MgO-SnO2. The results provide a new route for the design and preparation of composite oxide superbases. Furthermore, the solid superbases will facilitate a strategy for high-efficiency synthesis of polyfunctionalized 4H-pyrans.

Biocatalytic tandem multicomponent reactions for one-pot synthesis of 2-Amino-4H-Pyran library and in vitro biological evaluation

Gong, Qing-Tian,Liu, Yan-Hong,Wang, Na,Wang, Yun,Yang, Zeng-Jie,Yu, Xiao-Qi,Yu, Yuan

, (2020/05/18)

A simple, effective and ecofriendly biocatalytic method has been developed to construct 2-amino-4H-pyrans via tandem multi-component reaction (MCR) of aldehyde, malononitrile and ethyl acetoacetate in one pot. The catalytic activity of lipases in differen

Synthesis method of 2-amino-4H-pyran and derivative of 2-amino-4H-pyran

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Paragraph 0046-0049, (2019/10/01)

The invention discloses a synthesis method of 2-amino-4H-pyran and a derivative of the 2-amino-4H-pyran. According to the method, candida rugosa lipase (CRL) is adopted as a catalyst to initiate a tandem MCR reaction, and 2-amino-4H-pyran is synthesized i

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