304881-41-2

Basic information

• Product Name: 1,3-Dioxolan-2-one, 4-[(4-chlorophenyl)thio]-
• CAS NO: 304881-41-2
• Molecular Formula: C9H7ClO3S
• Molecular Weight: 230.672
• Mol File: 304881-41-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3-Dioxolan-2-one, 4-[(4-chlorophenyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Dioxolan-2-one, 4-[(4-chlorophenyl)thio]-(304881-41-2)
• EPA Substance Registry System: 1,3-Dioxolan-2-one, 4-[(4-chlorophenyl)thio]-(304881-41-2)

Safety Data

• Hazardous Substances Data: 304881-41-2(Hazardous Substances Data)

Upstream product

• 872-36-6 vinylene carbonate 
• 106-54-7 p-Chlorothiophenol 

Downstream Products

• 114435-02-8 monofluoroethylene carbonate 

Relevant articles and documents

Electrolytic partial fluorination of organic compound. Part: 53 Highly regioselective anodic mono- and difluorination of 4-arylthio-1,3-dioxolan-2-ones. A marked solvent effect on fluorinated product selectivity

Anodic fluorination of 4-arylthio-1,3-dioxolan-2-ones was investigated using various supporting fluoride salts and solvents. Their fluoro-desulfurization took place predominantly in Et4NF·5HF/CH2Cl2 while the use of Et4NF·4HF/DME resulted in α-fluorination, without the desulfurization, selectively. Electrolytic solvents affected markedly the product selectivity as compared with supporting fluoride salts. This is the first example of a solvent effect on the fluorinated product selectivity in the anodic fluorination.