30495-13-7Relevant academic research and scientific papers
Synthesis of 3-substituted 2-fluoro- And 2,2-difluoroaziridines
Van Hende, Eva,Verniest, Guido,Surmont, Riccardo,De Kimpe, Norbert
, p. 2935 - 2937 (2008/02/07)
A new route for the synthesis of stable 3-alkyl- and 3-aryl-2(,2)-(di) fluoroaziridines was developed by hydride reduction of novel α-bromo- and α-chloro-α(,α)-(di)fluoroketimines and subsequent ring closure of β-fluorinated β-chloro- and β-bromoamines. T
Synthesis of 2-fluoro- acids, esters, and amides from α-dicyanoepoxides
Amanetoullah, A. Ould,Chaabouni,Baklouti
, p. 1155 - 1161 (2007/10/03)
The opening of α-dicyanoepoxides by pyridine polyhydrofluoride yields polymerisable 2-fluorocyanoformyls which may be kept intact when diluated in dichloromethane or ether. These intermediates react with nucleophiles such as water, methanol or amines to give respectively 2-fluoroacids, esters or amides.
