30506-37-7Relevant academic research and scientific papers
Thioether ligand-enabled cationic palladium (II)-catalyzed electrophilic C-H arylation of α,β-unsaturated oxime ethers
Tamura, Osamu,Yamada, Takahiro,Hashimoto, Yoshimitsu,Tanaka Iii, Kosaku,Morita, Nobuyoshi
, p. 12315 - 12328 (2020/11/10)
The use of the cationic palladium(II) catalyst realized electrophilic C-H arylation of α,β-unsaturated O-SEM oximes with arylboronic acids. This Pd-catalyzed electrophilic C-H arylation is facilitated by employing alkyl aryl thioether ligands, and optimization of the ligand structure greatly improves the yield. The resulting α,β-unsaturated oximes would provide access to multisubstituted heterocyclic compounds.
