30513-14-5

Basic information

• Product Name: Rhodium(1+), bis[1,1'-(1,2-ethanediyl)bis[1,1-diphenylphosphine-κP]]-, (SP-4-1)-, perchlorate (1:1)
• Synonyms: Rhodium (1+), bis[ethylenebis[diphenylphosphine]]-, perchlorate
• CAS NO: 30513-14-5
• Molecular Formula: C52 H48 P4 Rh . Cl O4
• Molecular Weight: 999.204
• Mol File: 30513-14-5.mol
• Article Data: 1

Chemical Properties

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• CAS DataBase Reference: Rhodium(1+), bis[1,1'-(1,2-ethanediyl)bis[1,1-diphenylphosphine-κP]]-, (SP-4-1)-, perchlorate (1:1)(CAS DataBase Reference)
• NIST Chemistry Reference: Rhodium(1+), bis[1,1'-(1,2-ethanediyl)bis[1,1-diphenylphosphine-κP]]-, (SP-4-1)-, perchlorate (1:1)(30513-14-5)
• EPA Substance Registry System: Rhodium(1+), bis[1,1'-(1,2-ethanediyl)bis[1,1-diphenylphosphine-κP]]-, (SP-4-1)-, perchlorate (1:1)(30513-14-5)

Safety Data

• Hazardous Substances Data: 30513-14-5(Hazardous Substances Data)

Upstream product

• 54243-41-3 isoquinoline-N-oxide hydrate 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 
• 112312-48-8 [Rh(C₈H₁₂)(C₉H₇NO)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh(C₈H₁₂)(C₉H₇NO)2]ClO₄ 
• 99243-78-4 (cyclooctadiene)bis(4-methylquinoline N-oxide)rhodium(I) perchlorate 
• 119072-55-8 tert-butylisonitrile 
• 15043-47-7 [Rh(bis(diphenyl)phosphinoethane)₂][Cl] 

Downstream Products

• 29189-87-5 hydrido{1,2-bis-(diphenylphosphino)ethane}rhodium 
• 538-93-2 1-phenyl-2-methylpropane 

Relevant articles and documents

NOVEL CATIONIC RHODIUM(I) COMPLEXES CONTAINING OLEFINS AND SUBSTITUTED QUINOLINE N-OXIDES AS LIGANDS

2, silver perchlorate, and L' or L' and L'' gave , A, or , B, respectively, where L is cyclo-octatetraene (COT) or norbornadiene, L' is quinoline N-oxide (QNO) or its 4-methyl or 4-chloro derivative, and L'' is PPh3 or 4-(dimethylamino)pyridine; B was obtained from A when L'' = PPh3 + and excess ligand gave 2Rh>+ and +, while, with CO, dicarbonyl derivatives were obtained and + was isolated; with other ligands + resulted .