305347-72-2Relevant academic research and scientific papers
Synthesis, X-ray structure analysis and topochemical photopolymerization of 2,5-dimethoxyphenyl- and quinone-substituted octa-3,5-diynes
Irngartinger, Hermann,Skipinski, Markus
, p. 6781 - 6794 (2007/10/03)
The octa-3,5-diynes 3a-g have been synthesized. Subsequent oxidation of 3a-g gave the 1,8-quinone-substituted octa-3,5-diynes 4a-g. The molecular structures of the diynes α-3b, β-3b, 3c, 3e, 3f and 4f have been determined by X-ray diffraction. UV-irradiation of diyne 3c afforded in a single crystal-to-single crystal transformation the highly-ordered polymer 5 under topochemical control. The transformation of 3c into polymer 5 was observed by X-ray diffraction analysis. Irradiation of 4d yielded the first quinone-substituted intensive-blue poly(but-1-en-3-ynylene) 5, which turned red after work up. (C) 2000 Elsevier Science Ltd.
