30572-96-4Relevant academic research and scientific papers
SYNTHESIS OF 1,2-CYCLOALKANEDIOLS BY INTRAMOLECULAR TITANIUM-INDUCED PINACOL COUPLING
McMurry, John E.,Rico, Joseph G.
, p. 1169 - 1172 (2007/10/02)
Seven representative 1,2-cycloalkanediols of ring size 6-14 were prepared in high yield by titanium-induced pinacol coupling of dialdehydes.Cis stereochemistry predominated in six- and eight-membered rings, but trans products were formed in ring sizes ten and above.
METHODS FOR THE INTERCONVERSION OF PROTECTIVE GROUOPS. TRANSFORMATION OF MEM ETHERS INTO ISOPROPYLTHIOMETHYL ETHERS OR CYANOMETHYL ETHERS
Corey, E. J.,Hua, Duy H.,Seitz, Steven P.
, p. 3 - 6 (2007/10/02)
This letter describes methods for the synthesis of isopropylthiomethyl and cyanomethyl ethers from the corresponding MEM ethers and also a process for the cleavage of MEM or MOM ethers of 1,2- and 1,3-diols which avoids cyclization to formals.
