30608-09-4

Upstream product

• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 104976-44-5 1,6-Anhydro-2,3-di-O-benzyl-4-O-<(trifluormethyl)sulfonyl>-β-D-galactopyranose 
• 38184-10-0 phenyl 2,3,4,5-tetra-O-benzyl-1-thio-β-D-glucopyranoside 
• 80325-47-9 1,6-Anhydro-2,3-di-O-benzyl-β-D-glucopyranose 

Downstream Products

• 80325-50-4 Acetic acid (2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-(2,2,2-trichloro-acetimidoyloxy)-3-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-ylmethyl ester 
• 80325-50-4 Acetic acid (2R,3R,4S,5R,6S)-4,5-bis-benzyloxy-6-(2,2,2-trichloro-acetimidoyloxy)-3-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-ylmethyl ester 
• 80339-87-3 [(2R,3R,4S,5R,6S)-4,5-Bis-benzyloxy-6-((1R,2R,3S,4R,5R)-3,4-bis-benzyloxy-6,8-dioxa-bicyclo[3.2.1]oct-2-yloxy)-3-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yl]-methanol 
• 80325-51-5 Acetic acid (2R,3R,4S,5R,6S)-4,5-bis-benzyloxy-6-((1R,2R,3S,4R,5R)-3,4-bis-benzyloxy-6,8-dioxa-bicyclo[3.2.1]oct-2-yloxy)-3-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-ylmethyl ester 
• 80325-48-0 Acetic acid (2R,3R,4S,5R)-6-acetoxy-4,5-bis-benzyloxy-3-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-ylmethyl ester 

Relevant academic research and scientific papers

Thioperoxide-mediated activation of thioglycoside donors

Thioperoxide (1) in combination with trimethylsilyl trifluoromethanesulfonate (TMSOTf) provides a powerful thiophilic promoter system, capable of activating different thioglycosides. Both armed and disarmed thioglycosides were activated effectively in the

Anomeric O-Alkylation, 9. Disaccharide Synthesis via Anomeric O-Alkylation

Base-promoted reaction of tetra-O-benzyl-glucose 1a with secondary alkyl trifluoromethanesulfonates 2 and 3 in toluene provides in the presence of 15-crown-5 preferentially β-glycosides 2aβ and 3aβ, respectively, in high yields.For reactions carried out a