30669-24-0

Upstream product

• 73191-02-3 (tetrabutylammonium)[IrCl₂(CO)2] 
• 1486-28-8 diphenyl(methyl)phosphine 
• 74318-73-3 1-[Ir(H)(Cl)(CO)(PPh2Me)2]-7-CH3-1,7-(σdicarba-closo-dodecaborane(12)) 

Downstream Products

• 22853-20-9 (CH₃)3SnIrHClCO{P(C₆H₅)2CH₃}2 
• 28521-34-8 Cl(CO)Ir(P(C₆H₅)2CH₃)2S₂C₂(CF₃)2 
• 81178-13-4 IrCl(CO)(η2-CS2)(PMePh2)2 
• 82268-76-6 [(C₇F₈)IrCl(CO)(PCH₃(C₆H₅)2)2] 
• 28195-56-4 trans-carbonylchloro-bis(tri-(p-tolyl)phosphine)iridium(I) 
• 135972-49-5 Ir(CO)(OCH₃)(P(C₆H₄CH₃)3)(P(CH₃)(C₆H₅)2) 
• 135972-47-3 Ir(CO)(Cl)(P(C₆H₅)2CH₃)(P(C₆H₄CH₃)3) 
• 138666-27-0 Ir(CF₃SO₃)(CO)(PCH₃(C₆H₅)2)2 
• 38780-89-1 [IrCl(O₂C(CH₃)3)2(CO)(P(C₆H₅)2CH₃)2] 
• 20313-03-5 trans-[IrCl₂[C(O)CH₃](CO)(PMePh₂)2] 
• 82532-06-7 chlorobis(3-chlorobenzoato)bis(methyldiphenylphosphine)iridium(III) 

Relevant academic research and scientific papers

A high-yield synthetic approach to trans-[Ir(ER3)2(CO)X] (ER3=PMe3, PEt3, PPhMe2, PPh2Me, P(OMe)3, AsMe3, AsEt3, AsPh3, SbPh3; X=Cl, Br)

The complex [Ir(CO)2X2][NBu4] (X=Cl, Br) forms Vaska-type complexes, trans-[Ir(ER3)2(CO)X], when treated with two equivalents of aryl- or alkyl-phosphines, arsines, or stibines under a CO atmosphere. The synthesis is general for a wide range of phosphines, arsines, or stibines irrespective of the cone angle. For small cone-angle ligands, the initial addition of ligand to [Ir(CO)2X2][NBu4] is performed at low temperature. The synthesis and characterisation of three new Vaska-type complexes trans-[Ir(P(OMe)3)2(CO)Cl], trans-[Ir(AsMe3)2(CO)Cl], and trans-[Ir(AsEt3)2(CO)Cl] is also reported. Elsevier Science Ltd.