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[(κ2-P,P)-(C6H11)2PCH2CH2P(C6H11)2]Pt(SiMe2C6H4SiMe2) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

306975-78-0

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306975-78-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 306975-78-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,0,6,9,7 and 5 respectively; the second part has 2 digits, 7 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 306975-78:
(8*3)+(7*0)+(6*6)+(5*9)+(4*7)+(3*5)+(2*7)+(1*8)=170
170 % 10 = 0
So 306975-78-0 is a valid CAS Registry Number.

306975-78-0Downstream Products

306975-78-0Relevant academic research and scientific papers

Transition metal silyl complexes. Part 63. Influence of the phosphane ligands and the metal complex geometry on the silyl group exchange between L2Pt(SiMe2Ph)2 (L2 = R2PCH2CH2PR2 or 2PR3) and HSiR'3

Kalt, Dominique,Schubert, Ulrich

, p. 211 - 214 (2000)

The exchange of the silyl ligands upon reaction of [(κ2-P,P)-R2PCH2CH:PR2]Pt(SiMe2Ph)2 (R = Ph, Me, cyclohexyl) with HSi(OMe)3 or 1,2-bis(dimethylsilyl)benzene was investigated by NMR spectroscopy. The exchange rate is considerably lower than in the complexes cis-(R3P)2Pt(SiMe2Ph)2, and decreases in the order R = Ph > Me > cyclohexyl. No exchange was observed in the analogous reactions of trans-(R3P)2Pt(SiMe2Ph)2. The isomerization of cis-(PhMe2P)2Pt(SiMe2Ph)2 into trans-(PhMe2P)2Pt-(SiMe2Ph)2 is catalyzed by di- and oligosilanes. (C) 2000 Elsevier Science S.A.

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