3073-03-8

Basic information

• Product Name: 2-phenyltriphenylene
• Synonyms: 2-phenyltriphenylene
• CAS NO: 3073-03-8
• Molecular Weight: 304.391
• Mol File: 3073-03-8.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 2-phenyltriphenylene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-phenyltriphenylene(3073-03-8)
• EPA Substance Registry System: 2-phenyltriphenylene(3073-03-8)

Safety Data

• Hazardous Substances Data: 3073-03-8(Hazardous Substances Data)

Upstream product

• 34177-25-8 4-iodo-[1,1':3',1]terphenyl 
• 71-43-2 benzene 
• 24253-38-1 4-iodo-o-terphenyl 
• 536-74-3 phenylacetylene 
• 76129-24-3 2-iodo-1,1’:4’,1’’-terphenyl 
• 7073-69-0 2-(2-bromophenyl)propanol 
• 1591-31-7 4-iodo-biphenyl 
• 2113-51-1 2-iodobiphenyl 
• 591-50-4 iodobenzene 
• 90-41-5 2-phenylaniline 
• 76129-23-2 [1,1':4',1''-terphenyl]-2-amine 
• 615-43-0 2-iodophenylamine 
• 98-80-6 phenylboronic acid 
• 92-52-4 biphenyl 

Relevant articles and documents

Two-in-One Strategy for the Pd(II)-Catalyzed Tandem C-H Arylation/Decarboxylative Annulation Involved with Cyclic Diaryliodonium Salts

We report here a two-in-one strategy for the Pd(II)-catalyzed tandem C-H arylation/decarboxylative annulation between readily available cyclic diaryliodonium salts and benzoic acids. The carboxylic acid functionality can be used as both a directing group for the ortho-C-H arylation and the reactive group for the tandem decarboxylative annulation. By a step-economical double cross-coupling annulation procedure, the privileged triphenylene frameworks were efficiently constructed, which have potential applications in material chemistry.

Palladium Catalyzed C-I and Vicinal C-H Dual Activation of Diaryliodonium Salts for Diarylations: Synthesis of Triphenylenes

Using the synthetic strategy of palladium-catalyzed dual activation of both C-I and vicinal C-H bonds of diaryliodonium salts, we report an approach for direct diarylations of 2-bromobiphenyls or bromobenzenes. As a result, a wide range of triphenylenes with various substituents have been synthesized in good yields. These triphenylenes are expected to be employed in the "bottom-up" synthesis of functional aromatic molecules in material science.

C-C Bond (Hetero)arylation of Ring-Fused Benzocyclobutenols and Application in the Assembly of Polycyclic Aromatic Hydrocarbons

Herein, we disclose a new and efficient synthetic approach to triphenylene-based polycyclic aromatic hydrocarbons (PAHs) from ring-fused benzocyclobutenols (RBCBs) through the cleavage of the C-C σ-bond. Two key transformations are involved: (a) palladium-catalyzed C-C bond (hetero)arylation of RBCBs; and (b) Lewis acid-promoted intramolecular annulation leading to complex polycyclic compounds. A variety of multiply substituted triphenylenes and derivatives are obtained in synthetically useful yields.