307345-14-8Relevant academic research and scientific papers
Synthesis of 2-halo-2H-azirines
Pinho E Melo, Teresa M.V.D,Lopes, Cláudia S.J,Cardoso, Ana L,Rocha Gonsalves, Anto?nio M.D'A
, p. 6203 - 6208 (2007/10/03)
α-Oxophosphonium ylides react with N-chlorosuccinimide, N-bromosuccinimide and N-iodosuccinimide in the presence of azidotrimethylsilane giving the corresponding haloazidoalkenes which were completely converted to the 2-halo-2H-azirines on heating in heptane.
Synthesis and reactivity of 2-halo-2H-azirines towards nucleophiles
Pinho e Melo,Lopes,Gonsalves
, p. 7217 - 7220 (2007/10/03)
Nucleophilic substitution reactions of 2-halo-2H-azirine with potassium phthalimide and aniline allowed the preparation of new substituted 2H-azirines. The reactions of 2-bromo-3-phenyl-2H-azirine-2-carboxylate with methylamine led to the synthesis of α-diimines and from the reaction with water, a 3-oxazoline was obtained. (C) 2000 Published by Elsevier Science Ltd.
