30736-07-3

Basic information

• Product Name: DI-TERT-BUTYLSILANE
• Synonyms: DI-T-BUTYL SILANE;Ditertiarybutylsilane;Di-tert-butylsilane 97%;bis(1,1-dimethylethyl)-silan;DI-TERT-BUTYLSILANE
• CAS NO: 30736-07-3
• Molecular Formula: C₈H₂₀Si
• Molecular Weight: 144.33
• Product Categories: Si (Classes of Silicon Compounds);Si-H Compounds;Organometallic Reagents;Organosilicon;Others;Chemical Synthesis;Organometallic Reagents
• Mol File: 30736-07-3.mol
• Article Data: 1

Chemical Properties

• Melting Point: −38 °C(lit.)
• Boiling Point: 129-130 °C(lit.)
• Flash Point: 28 °F
• Appearance: /
• Density: 0.729 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.42(lit.)
• CAS DataBase Reference: DI-TERT-BUTYLSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: DI-TERT-BUTYLSILANE(30736-07-3)
• EPA Substance Registry System: DI-TERT-BUTYLSILANE(30736-07-3)

Safety Data

• Hazard Codes: F
• Statements: 11
• Safety Statements: 16-33
• RIDADR: UN 1993 3/PG 1
• WGK Germany: 3
• TSCA: No
• HazardClass: 3
• PackingGroup: II
• Hazardous Substances Data: 30736-07-3(Hazardous Substances Data)

Usage

Uses

Di-tert-butylsilane can be used as a reagent to synthesize: 1,1-di-tert-butyl-N-phenylsilanamine by dehydrogenative coupling with aniline in the presence of supported gold catalyst. Benzyloxy di-tert-butylsilane by dehydrocoupling of benzyl alcohol using NaOH as a catalyst. Di-tert-butyl(3-cyclohexylprop-1-yn-1-yl)silane by silylation reaction with 2-propyn-1-ylcyclohexane using alkali metal hydroxide as a catalyst.

Application

Sterically-hindered silane reducing agent.

InChI:InChI=1/C8H18IS/c1-7(2,3)9-10-8(4,5)6/h1-6H3/q-1

Upstream product

• 59409-86-8 1,1,2,2-tetra-tert-butyldisilane 
• 18171-74-9 tert-butyltrichlorosilane 
• 594-19-4 tert.-butyl lithium 

Downstream Products

• 906373-73-7 [(1,2-bis(dicyclohexylphosphino)ethane)Pd(H)SiH(t-Bu)2] 
• 1042695-78-2 (E)-di-tert-butyl-(2-methyl-1,3-diphenylallyloxy)silane 
• 1042695-80-6 2,2-di-tert-butyl-4-methyl-3,5-diphenyl-2,5-dihydro-1,2-oxasilole 
• 1223451-95-3 (E)-di-tert-butyl[(2-methyl-1-phenylhex-2-en-1-yl)oxy]silane 
• 1223452-28-5 (E)-di-tert-butyl[(2-ethylidene-1-phenylpentyl)oxy]silane 
• 1223452-58-1 C₂₁H₄₂OSi 
• 1223452-63-8 C₂₁H₄₂OSi 
• 1223452-00-3 (E)-di-tert-butyl[(2,4-dimethyl-1-phenylpent-2-en-1-yl)oxy]silane 
• 1260137-01-6 2,2-di-tert-butyl-4-methyl-1,3-dioxa-4-phenyl-2-silacyclohexane 
• 1260137-02-7 1-di-tert-butylsilyloxy-3-phenylbutan-3-ol 
• 1254592-85-2 C₁₈H₃₆OSi 
• 1254592-79-4 C₁₈H₃₈OSi 
• 13321-36-3 di-tert-butylsilanediol 
• 56310-22-6 di-tert-butylhydridosilanol