307966-18-3

Upstream product

• 2716-23-6 bicyclo[2.2.2]octan-2-one 
• 882-33-7 diphenyldisulfane 
• 108-98-5 thiophenol 
• 278-84-2 2,3-epoxybicyclo<2.2.2>oct-2-ene 

Relevant academic research and scientific papers

Experimental evidence for negative hyperconjugation as a component of the polar effect: Variation of the ease of α-sulfonyl carbanion formation with the orientation of a β-alkoxy substituent

We report evidence for a strongly geometry-dependent substituent effect. The rate constants for H-D exchange of the α-hydrogens, (k(exch))OR, in a set of 19 β-alkoxy sulfones of known, fixed (or strongly preferred) H-C(α)-C(β)-OR torsion angles have been

Application of a three-carbon ring expansion process to bridged bicyclic systems

Experimental data in combination with MMFF94 and AM1 calculations offer a model for predicting the viability of Trost's three-carbon ring expansion on bicyclic systems.