308122-91-0Relevant academic research and scientific papers
High-rate accelerations in oxy-Cope rearrangements induced by sulfur substitution: Kinetic study involving electronically and geometrically differentiated 1-alkenyl-2-(Z-1-propenyl)-7,7-dimethyl-exo-norbornan-2-ols
Paquette,Reddy,Vayner,Houk
, p. 10788 - 10794 (2000)
The rates of anionically promoted oxy-Cope rearrangement of five structurally related exonorbornanols have been determined. A critical difference in the substitution pattern of these substrates is the presence or absence of oxygen or sulfur functionality
