308132-07-2

Basic information

• Product Name: [Fe2(CO)6(μ-P(C6H5)2)(μ-η1(P):η3(C):η1(C)-(C6H5)CCC(H)CH3CH=CC6H5C(P(C6H5)2))]
• CAS NO: 308132-07-2
• Molecular Weight: 708.27
• Mol File: 308132-07-2.mol

Chemical Properties

• CAS DataBase Reference: [Fe2(CO)6(μ-P(C6H5)2)(μ-η1(P):η3(C):η1(C)-(C6H5)CCC(H)CH3CH=CC6H5C(P(C6H5)2))](CAS DataBase Reference)
• NIST Chemistry Reference: [Fe2(CO)6(μ-P(C6H5)2)(μ-η1(P):η3(C):η1(C)-(C6H5)CCC(H)CH3CH=CC6H5C(P(C6H5)2))](308132-07-2)
• EPA Substance Registry System: [Fe2(CO)6(μ-P(C6H5)2)(μ-η1(P):η3(C):η1(C)-(C6H5)CCC(H)CH3CH=CC6H5C(P(C6H5)2))](308132-07-2)

Safety Data

• Hazardous Substances Data: 308132-07-2(Hazardous Substances Data)

Upstream product

• 536-74-3 phenylacetylene 

Relevant articles and documents

Reactions of alkynes with [Fe2(CO)6(μ-PPh2){μ-η 1:η2α,β=(H)C α=Cβ=CγH2}]: Formation of diphenylvinylphosphine-functionalized vinyl carbenes via carbon-carbon and carbon-phosphorus bond formation and hydrogen migration

Reaction of [Fe2(CO)6(μ-PPh2){μ-η 1:η2α,β-(H)C α=Cβ=CγH2}] (1) with PhC=CPh results in allenyl-alkyne-phosphido coupling to give [Fe2(CO)6(μ-PPh2){μ-η 1(P):η3(C):η 1(C)-C(Ph)C-(Ph)C(H)C(=CH2)PPh2}] (2), bridged by a diphenylvinylphosphine-substituted vinyl carbene. Under similar conditions 1 reacts with PhC=CMe to give an equal mixture of the two possible regioisomers