308274-29-5Relevant academic research and scientific papers
Intramolecular iron(II)-catalyzed nitrogen transfer reactions of unsaturated alkoxycarbonyl azides: A facile and stereoselective route to 4,5-disubstituted oxazolidinones
Bach, Thorsten,Schlummer, Bjoern,Harms, Klaus
, p. 2581 - 2594 (2001)
Intramolecular Fe11-catalyzed reactions of various unsaturated alkoxycarbonyl azides are described. The reactions occur in the presence of stoichiometric amounts of trimethyl silyl chloride employing ethanol as the solvent. The corresponding 2-
Intramolecular iron(II)-catalyzed addition reactions of propargyloxycarbonyl azides
Bach,Schlummer,Harms
, p. 1330 - 1332 (2007/10/03)
The Fe(II)-catalyzed dediazotation of the propargyl-oxycarbonyl azides 2-4 was studied. In the case of phenyl- (2) and n-butyl-substituted (3) alkynes the products 5 and 6 of an intramolecular syn-aminochlorination were isolated in excellent yields (81-99
