308274-39-7Relevant academic research and scientific papers
FeCl2-catalyzed intramolecular chloroamination reactions
Danielec, Holger,Kluegge, Jan,Schlummer, Bjoern,Bach, Thorsten
, p. 551 - 556 (2006)
2-Alkenyloxycarbonyl azides 1 and 2-alkynyloxycarbonyl azides 3 undergo in the presence of trimethylsilyl chloride and catalytic amounts of FeCl 2 an intramolecular chloroamination (aminochlorination) reaction (Procedure 1). The corresponding o
Intramolecular iron(II)-catalyzed nitrogen transfer reactions of unsaturated alkoxycarbonyl azides: A facile and stereoselective route to 4,5-disubstituted oxazolidinones
Bach, Thorsten,Schlummer, Bjoern,Harms, Klaus
, p. 2581 - 2594 (2007/10/03)
Intramolecular Fe11-catalyzed reactions of various unsaturated alkoxycarbonyl azides are described. The reactions occur in the presence of stoichiometric amounts of trimethyl silyl chloride employing ethanol as the solvent. The corresponding 2-
Intramolecular iron(II)-catalyzed addition reactions of propargyloxycarbonyl azides
Bach,Schlummer,Harms
, p. 1330 - 1332 (2007/10/03)
The Fe(II)-catalyzed dediazotation of the propargyl-oxycarbonyl azides 2-4 was studied. In the case of phenyl- (2) and n-butyl-substituted (3) alkynes the products 5 and 6 of an intramolecular syn-aminochlorination were isolated in excellent yields (81-99
