308358-34-1Relevant academic research and scientific papers
Diastereoselective peroxidation of derivatives of Baylis–Hillman adducts
Zuckerman, Dylan S.,Woerpel
supporting information, p. 4118 - 4129 (2019/06/24)
Cyclic derivatives of Baylis–Hillman adducts were synthesized. Cobalt-catalyzed peroxidation of these cyclic lactones afforded silyl peroxides in diastereomeric ratios ranging from 91:9 to 97:3.
2 H-Chromene-3-carboxylic Acid Synthesis via Solvent-Controlled and Rhodium(III)-Catalyzed Redox-Neutral C-H Activation/[3 + 3] Annulation Cascade
Zhou, Zhi,Bian, Mengyao,Zhao, Lixin,Gao, Hui,Huang, Junjun,Liu, Xiawen,Yu, Xiyong,Li, Xingwei,Yi, Wei
supporting information, p. 3892 - 3896 (2018/07/22)
An efficient and redox-neutral synthesis of 2H-chromene-3-carboxylic acids from N-phenoxyacetamides and methyleneoxetanones has been realized via a solvent-controlled and rhodium(III)-catalyzed C-H activation/unusual [3 + 3] annulation sequence. This tran
Pd-Catalyzed Acyl C-O Bond Activation for Selective Ring-Opening of α-Methylene-β-lactones with Amines
Malapit, Christian A.,Caldwell, Donald R.,Sassu, Nicole,Milbin, Samuel,Howell, Amy R.
supporting information, p. 1966 - 1969 (2017/04/28)
A Pd-catalyzed ring-opening of β-lactones with various types of amines (primary, secondary, and aryl) to provide β-hydroxy amides with excellent selectivity toward acyl C-O bond cleavage is reported. The utility of this protocol is demonstrated in an asym
Unusual, strained heterocycles: 3-Alkylidene-2-methyleneoxetanes from Morita-Baylis-Hillman-type adducts
Martinez, Isamir,Andrews, Alexander E.,Emch, Joseph D.,Ndakala, Albert J.,Wang, Jun,Howell, Amy R.
, p. 399 - 402 (2007/10/03)
(Matrix presented) 3-Alkylidene-2-methyleneoxetanes have been prepared by treating α-alkylidene-β-lactones, derived from Morita-Baylis-Hillman-type adducts, with dimethyltitanocene. Preliminary studies of the reactivity of these little known, strained het
A novel precipitating auxiliary approach to the purification of Baylis-Hillman adducts
Bosanac,Wilcox
, p. 1618 - 1619 (2007/10/03)
Diaryl alkene alcohol 1 is a 'precipiton', a precipitating auxiliary that is used to aid the isolation of Baylis-Hillman adducts.
