3096-52-4

Basic information

• Product Name: 2-NITROFLUORENONE
• Synonyms: 2-NITRO-9-FLUORENONE, 98+%;2-nitrofluoren-9-one;2-NITROFLUORENONE;2-NITRO-9-FLUORENONE;2-nitro-9h-fluoren-9-on;2-Nitro-9H-fluoren-9-one;9-Fluorenone, 2-nitro;9H-Fluoren-9-one, 2-nitro-
• CAS NO: 3096-52-4
• Molecular Formula: C₁₃H₇NO₃
• Molecular Weight: 225.2
• Product Categories: Fluorenones;C13 to C14;Carbonyl Compounds;Ketones;Fluorenes, Flurenones;Fluorenes & Fluorenones
• Mol File: 3096-52-4.mol
• Article Data: 3

Chemical Properties

• Melting Point: 222-223 °C(lit.)
• Boiling Point: 366.7°C (rough estimate)
• Flash Point: 215.1 °C
• Appearance: /Solid
• Density: 1.2785 (rough estimate)
• Vapor Pressure: 3.13E-07mmHg at 25°C
• Refractive Index: 1.4800 (estimate)
• CAS DataBase Reference: 2-NITROFLUORENONE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-NITROFLUORENONE(3096-52-4)
• EPA Substance Registry System: 2-NITROFLUORENONE(3096-52-4)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• RTECS: LL9091000
• Hazardous Substances Data: 3096-52-4(Hazardous Substances Data)

Usage

Chemical Properties

Bright yellow needles

General Description

2-Nitro-9-fluorenone is a mutagenic photoproduct of u.v.a.-irradiated 2-aminofluorene. 2-Nitro-9-fluorenone was isolated from diesel-exhaust particles using a two-step fractionation scheme consisting of Sephadex LH20 chromatography and silica-gel thin-layer chromatography. Submicromolar concentrations of 2-nitro-9-fluorenone were quantitated by mercury meniscus modified silver solid amalgam electrode combined with direct current voltammetry or differential pulse voltammetry.

InChI:InChI=1/C13H7NO3/c15-13-11-4-2-1-3-9(11)10-6-5-8(14(16)17)7-12(10)13/h1-7H

Upstream product

• 28149-15-7 9-Hydroxy-2-nitrofluorene 
• 41085-71-6 bromamine T 
• 7664-93-9 sulfuric acid 
• 153-78-6 2-aminofluorene 
• 486-25-9 9-fluorenone 

Downstream Products

• 33417-27-5 2-amino-9-hydroxyfluorene 
• 111796-34-0 (2-nitro-fluoren-9-ylidene)-p-tolyl-amine 
• 7148-37-0 2.9-Diamino-fluoren 
• 75158-95-1 2-nitro-9-(N-phenyl)-iminofluorene 
• 102241-35-0 (4-ethyl-phenyl)-(2-nitro-fluoren-9-yliden)-amine 
• 607-57-8 2-nitro-9H-fluorene 
• 3096-57-9 2-amino-9-fluorenone 
• 784-50-9 fluorenone-2-carboxylic acid 
• 18158-43-5 2-(dimethylamino)-9H-fluoren-9-one 
• 58557-62-3 2-bromo-7-nitro-9H-fluoren-9-one 
• 38088-95-8 8-methoxy-phenanthridin-6-ol 
• 109935-08-2 N-(3-nitro-9-oxo-fluoren-2-yl)-benzamide 
• 42135-36-4 N-(9-oxo-fluoren-2-yl)-benzamide 
• 88387-73-9 9-Oxo-2-amino-7-nitrofluorene 

Relevant articles and documents

Selective oxidation of aromatic amines to nitro derivatives using potassium iodide-tert-butyl hydroperoxide catalytic system

The direct oxidation of aromatic primary amines to the corresponding nitro compounds selectively in 47-98% yields has been achieved by using potassium iodide as catalyst and tert-butyl hydroperoxide as the external oxidant. The present catalytic system works well for both electron-rich and electron-poor substrates.

Kinetics and Mechanism of Oxidation of Fluoren-9-ol and Substituted Fluoren-9-ols by Bromamine-T

The title reactions have been investigated in aq. acetic acid medium both in the presence and absence of perchloric acid.The reactions are first order each in and under both the conditions.There is unit dependence in perchloric acid.The effects of change in polarity of the solvent medium, added toluene-p-sulphonamide and sodium perchlorate have been studied.The reaction exhibits kinetic isotope effect (kH/kD = 2.2).Hammett ρ is found to be -2.8.Activation parameters have been evaluated.A mechanism consistent with rate data has been proposed.