309939-68-2Relevant academic research and scientific papers
Synthesis, crystal structure, and thermal property of [N′-(2-hydroxy- 3-methoxybenzylidene)-2-methoxybenzohydrazonato](methanol)(methoxy) oxovanadium(V)
Wang, Jun-Min,Liu, Hui-Min,Zhang, Dong-Nuan,Cui, Peng-Lei,Ma, Jing-Jun
, (2014)
The aroylhydrazone Schiff base ligand N'-(2-hydroxy-3-methoxybenzylidene)- 2-methoxybenzohydrazide (H2L) reacts with VO(acac)2 in methanol gave the complex [N′-(2-hydroxy-3-methoxybenzylidene)-2- methoxybenzohydrazonato] (methanol) (
Synthesis, crystal structure, and insulin-like activity of [N′-(2-hydroxy-3-methoxybenzylidene)-2-methoxybenzohydrazonato](1,10-phenanthroline)oxovanadium(IV) methanol solvate
Meng, Xu-Feng,Liu, Qi-Feng,Liu, Ji-Lai,Sun, Ming-Hui,Ma, Jing-Jun
, p. 1585 - 1589 (2017)
The aroylhydrazone Schiff base ligand N′-(2-hydroxy-3-methoxybenzylidene)-2-methoxybenzohydrazide (H2L) reacts with VO(acac)2 and 1,10-phenanthroline (Phen) in methanol to give the complex [N′-(2-hydroxy-3-methoxybenzylidene)-2-methoxybenzohydrazonato](1,10-phenanthroline)oxovanadium(IV) methanol solvate, [VIVOL(Phen)]·CH3OH. The structure of the complex was characterized by elemental analyses and IR spectroscopic method in the solid state. Single-crystal X-ray analysis was also performed. The complex crystallized in the triclinic space group P-1, with unit cell dimensions a = 9.220(3) ?, b = 9.382(3) ?, c = 16.593(5) ?, α = 73.900(5)°, β = 78.618(6)°, γ = 84.959(6)°, V = 1351.1(7) ?3, Z = 2, R1 = 0.0837, and wR2 = 0.0751. The vanadium(V) atom in the complex is six-coordinated with an octahedral geometry. Thermal stability as well as the insulin-like activity of the complex have been determined.
Two water-coordinated mononuclear molybdenum(VI) OXO complexes with similar tridentate hydrazone ligands: Synthesis and crystal structures
Qian, Shao-Song,Zhen, Miao-Miao,Zhao, Yue,Zhang, Na,You, Zhong-Lu,Zhu, Hai-Liang
, p. 1647 - 1650 (2013)
Reaction of [MoO2(acac)2] (where acac = acetylacetonate) with two similar hydrazone ligands in methanol yielded two water coordinated mononuclear molybdenum(VI) oxo complexes with general formula [MoO2L(OH2)], w
