310-17-8Relevant academic research and scientific papers
Synthesis of aryltriethoxysilanes via rhodium(I)-catalyzed cross-coupling of aryl electrophiles with triethoxysilane
Murata, Miki,Yamasaki, Hiyoruki,Ueta, Tsukasa,Nagata, Masayuki,Ishikura, Masanori,Watanabe, Shinji,Masuda, Yuzuru
, p. 4087 - 4094 (2008/01/03)
The general and efficient silylation of aryl halides has been developed utilizing triethoxysilane and a rhodium catalyst. The substrate scope is broad and includes ortho-, meta-, and para-substituted electron-rich and -deficient aryl iodides. In addition, the silylation of aryl bromides and fluoroalkanesulfonates proceeded in the presence of tetra-n-butylammonium iodide.
Rhodium(I)-Catalyzed Silylation of Aryl Halides with Triethoxysilane: Practical Synthetic Route to Aryltriethoxysilanes
Murata, Miki,Ishikura, Masanori,Nagata, Masayuki,Watanabe, Shinji,Masuda, Yuzuru
, p. 1843 - 1845 (2007/10/03)
(Equation Presented) The specific silylation of aryl iodides and bromides with triethoxysilane (EtO)3SiH in the presence of NEt3 and a catalytic amount of [Rh-(cod)(MeCN)2]BF4 provides the corresponding aryltriethoxysilanes in high yield.
