310455-07-3Relevant articles and documents
Selective oxygen capture in lithium zincate chemistry: The syntheses and solid-state structures of (μ-O)Zn4[N(2-C5H4N)Bz]6 and Bu(t)(μ3-O)Li3(μ6-O)Zn3[N(2-C5H4N)Me]6 (Bz = benzyl)
Davies,Linton,Snaith,Wheatley
, p. 1819 - 1820 (2007/10/03)
Sequential reaction of ZnMe2 with the (2-pyridyl)amines HN(2-C5H4N)R (R = Bz = benzyl 1, Me 2), Bu(t)Li and oxygen affords species which demonstrate oxo-encapsulation {(μ4-O)Zn4[N(2-C5H4N)Bz]6 3}, and both encapsulation and insertion into a C-Li bond {Bu(t)(μ3-O)Li3(μ6-O)Zn3[N(2-C5H4N)Me]6 4}; in the solid-state 4 has a new type of facisomeric (μ6-O)M3M'3 octahedral core.