31078-91-8

Basic information

• Product Name: allyldichlorophosphine
• Synonyms: allyldichlorophosphine
• CAS NO: 31078-91-8
• Molecular Weight: 142.952
• Mol File: 31078-91-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: allyldichlorophosphine(CAS DataBase Reference)
• NIST Chemistry Reference: allyldichlorophosphine(31078-91-8)
• EPA Substance Registry System: allyldichlorophosphine(31078-91-8)

Safety Data

• Hazardous Substances Data: 31078-91-8(Hazardous Substances Data)

Upstream product

• 31480-07-6 allylbis(diethylamino)phosphine 

Relevant articles and documents

ZUR KENNTNIS DER ORGANOPHOSPHORVERBINDUNGEN XXIII. UEBER ALKENYLSUBSTITUIERTE AMINO-BZW. HALOGENPHOSPHANE UND VERSUCHE ZUM INTRAMOLEKULAREN PHOSPHINIDENABFANG

Aminophosphanes RP(NEt2)2 and R2P(NEt2), obtained from alkenyl Grignard compounds RMgX (R = -CH=CH2, -CH2CH=CH2, o-(CH2=CH)C6H4-, o-(CH2=CHCH2)C6H4-) and aminochlorophosphanes, reacted smoothly with hydrogen halide to give alkenylhalogenophosphanes RPX2 and R2PX (X = Cl, Br).Properties and reactions of some of these compounds, e.g. with S8, H2O2, H2O and LiAlH4 are reported.On reaction of RPX2 with magnesium only alkenylcyclophosphanes (RP)n were obtained while heterocycles as possible products of an intramolecular reaction of intermediately formed phosphinidenes were not observed.