31121-12-7Relevant academic research and scientific papers
Synthesis of Different Classes of Six-Membered Gold(I) NHC Complexes by the Isonitrile Route
Wurm, Thomas,Mulks, Florian,B?hling, Constantin R. N.,Riedel, Dominic,Zargaran, Poorya,Rudolph, Matthias,Rominger, Frank,Hashmi, A. Stephen K.
, p. 1070 - 1078 (2016)
Different types of six-membered N-heterocyclic gold carbene complexes were prepared by using gold(I) isonitrile complexes as precursors in combination with suitably functionalized amines. The simple procedures provide an easy access to not only unsymmetrically substituted saturated carbene complexes but rarely reported types of carbene complexes such as six-membered N-heterocyclic oxo-carbene complexes, and six-membered partly unsaturated ligands can be obtained following the strategy.
Templated assembly of medium cyclic ethers: Via exo-trig nucleophilic cyclization of cyclopropenes
Alnasleh, Bassam K.,Rubina, Marina,Rubin, Michael
supporting information, p. 7494 - 7496 (2016/06/14)
A novel method for the assembly of medium heterocycles via an intramolecular nucleophilic addition to cyclopropenes generated in situ from the corresponding bromocyclopropanes is described. The exo-trig nucleophilic cyclizations were shown to proceed very
Diastereoselectivity control in formal nucleophilic substitution of bromocyclopropanes with oxygen- and sulfur-based nucleophiles
Banning, Joseph E.,Prosser, Anthony R.,Alnasleh, Bassam K.,Smarker, Jason,Rubina, Marina,Rubin, Michael
experimental part, p. 3968 - 3986 (2011/07/08)
A diastereoconvergent formal nucleophilic substitution of bromocyclopropanes with oxygen- and sulfur-based nucleophiles is described. The reaction proceeds via in situ formation of a highly reactive cyclopropene intermediate and subsequent diastereoselect
Indirect monoalkylation of primary and secondary amines by reductive decyanation of α-aminonitriles with sodium cyanoborohydride-mercury bis(trifluoroacetate)
Sassaman, Mark B.
, p. 10835 - 10840 (2007/10/03)
Secondary and tertiary amines are prepared from α-aminonitriles by selective reductive cleavage of the cyanide moiety. The α-aminonitriles in this case, function as 'masked' imine or iminium ions and are 'unmasked' by mercury(II) in the presence of sodium cyanoborohydride to obtain the reduced product. Secondary amines may be prepared indirectly from primary amines in good yield without danger of over alkylation.
SIMPLE SYNTHESIS OF 3-(N-ALKYLAMINO)-1-PROPANOLS
Artyushin, O. I.,Petrovskii, P. V.,Mastryukova, T. A.,Kabachnik, M. I.
, p. 1911 - 1913 (2007/10/02)
Various 3-(N-alkylamino)-1-propanols were obtained by the lithium aluminum hydride reduction of the products of the reaction of 3-amino-1-propanol with carbonyl compounds.This method for the synthesis of aminopropanols is applicable in the case of optimal electrophilicity of the carbonyl component.
Synthesis and Kinetics of the Formation of N-Substituted Cyclic Sulfinamides from Secondary Amine Disulfides
Wagner, Barbara J.,Doi, Joyce Takahashi,Musker, W. Kenneth
, p. 4156 - 4162 (2007/10/02)
N-substituted cyclic saturated sulfinamides were prepared from two secondary amine disulfides, 3-propyl disulfide and 3-(cyclohexylamino)propyl disulfide, and two bicyclic sulfinamides were made from 2-(2-piperidyl)ethyl disulfide an
