311780-53-7Relevant academic research and scientific papers
Novel single or double insertion of alkynes into rhodium- and iridium-oxygen or -phosphorus atom bonds and transannular addition of 1-alkynes between the rhodium atom and the ipso-carbon atom of the phosphorus ligand
Yamamoto, Yasuhiro,Sugawara, Kenichiro,Han, Xiao-Hong
, p. 195 - 211 (2007/10/03)
Reactions of Cp*MCl(MDMPP-P,O) (1a: M = Rh; 1b: M = Ir; MDMPP-P,O = PPh2(C6H3-2-MeO-6-O)) or Cp*MCl(BDMPP-P,O) (2a: M = Rh; 2b: M = Ir; BDMPP-P,O = PPh(C6H3-2,6-(MeO)2)(C6H
Novel insertion of ethynylbenzene derivatives bearing an electron-withdrawing substituent at the 4-position into a P-C bond and their transannular insertion between a metal atom and an //?.s0-carbon atom of the phosphine ligandf
Yamamoto, Yasuhiro,Sugawara, Kcnichiro
, p. 2896 - 2897 (2007/10/03)
Reactions of Cp*MCl(P-O) (M = Rh, Ir) bearing P-O coordination with ethynylbenzene derivatives having an electron-withdrawing group in the presence of a PF6 anion result in either insertion into a P-C bond or a transannular addition between a metal and an ipso-carbon of the phosphine. The Royal Society of Chemistry 2000.
