311780-55-9Relevant academic research and scientific papers
Novel insertion of ethynylbenzene derivatives bearing an electron-withdrawing substituent at the 4-position into a P-C bond and their transannular insertion between a metal atom and an //?.s0-carbon atom of the phosphine ligandf
Yamamoto, Yasuhiro,Sugawara, Kcnichiro
, p. 2896 - 2897 (2000)
Reactions of Cp*MCl(P-O) (M = Rh, Ir) bearing P-O coordination with ethynylbenzene derivatives having an electron-withdrawing group in the presence of a PF6 anion result in either insertion into a P-C bond or a transannular addition between a metal and an ipso-carbon of the phosphine. The Royal Society of Chemistry 2000.
