312313-49-8

Basic information

• Product Name: o-(2-Phenylpropanoyl)-N-(3,3,4,4-tetramethylthietan-2-ylidene)aniline
• Synonyms: o-(2-Phenylpropanoyl)-N-(3,3,4,4-tetramethylthietan-2-ylidene)aniline
• CAS NO: 312313-49-8
• Molecular Weight: 367.512
• Mol File: 312313-49-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: o-(2-Phenylpropanoyl)-N-(3,3,4,4-tetramethylthietan-2-ylidene)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: o-(2-Phenylpropanoyl)-N-(3,3,4,4-tetramethylthietan-2-ylidene)aniline(312313-49-8)
• EPA Substance Registry System: o-(2-Phenylpropanoyl)-N-(3,3,4,4-tetramethylthietan-2-ylidene)aniline(312313-49-8)

Safety Data

• Hazardous Substances Data: 312313-49-8(Hazardous Substances Data)

Upstream product

• 563-79-1 2,3-Dimethyl-2-butene 
• 312313-34-1 3-phenyl-1-(2-thioxobenzo[d]oxazol-3(2H)-yl)propan-1-one 

Downstream Products

• 204649-38-7 2-[(3,3,4,4-tetramethylthietan-2-ylidene)amino]phenyl acetate 
• 312313-52-3 o-Hydroxy-N-(3,3,4,4-tetramethylthietan-2-ylidene)aniline 

Relevant articles and documents

Photochemical reactions of N-acylbenzoxazole-2-thiones

The photochemical reactions of N-acylbenzoxazole-Z-thiones 1 are examined. Irradiation of N-acylbenzoxazole-2-thiones 1 in the presence of a variety of alkenes 2 yields 2-substituted benzoxazoles 3-20 and/or the unexpected products, iminothietanes 21-29 by intramolecular trapping of the acyl group by thiolate anion of the zwitterionic intermediate I and by the phenolate anion of the zwitterionic intermediate II, respectively, derived from the spirocyclic aminothietanes AT which are formed by regioselective [2+2] cycloaddition of the carbon-sulfur double bond of 1 to the alkene double bond. The Royal Society of Chemistry 2000.