312329-86-5

Upstream product

• 1206-41-3 N-(2-methylallyl)-4-toluenesulfonamide 
• 1437788-88-9 C₂₂H₃₅NO₂SSi 
• 312329-76-3 N-Formyl-4-methyl-N-(2-methyl-allyl)benzenesulfonamide 
• 70-55-3 toluene-4-sulfonamide 
• 4917-56-0 N-formyl-N-tosylamide 
• 312329-81-0 N-(2,2-dichlorovinyl)-N-(2-methylallyl)-4-methyl-benzenesulfonamide 

Downstream Products

• 349458-89-5 4-methyl-N-(2-methylallyl)-N-[(E)-3-(4,4,5,5-tetramethyl[1,3,2]dioxaborolan-2-yl)-vinyl]-4-benzenesulfonamide 
• 349458-91-9 4-methyl-N-(2-methylallyl)-N-[(E)-3-(4,4,5,5-tetramethyl[1,3,2]dioxaborolan-2-yl)-propenyl]-4-benzenesulfonamide 

Relevant academic research and scientific papers

Metal-free C8-H functionalization of quinolineN-oxides with ynamides

The metal-free C8-H functionalization of quinolineN-oxides with ynamides is unveiled for the first time by the intramolecular Friedel-Crafts-type reaction of quinolyl enolonium intermediates generated from Br?nsted acid-catalyzed addition of quinolineN-ox

Generation of rhodium(I) carbenes from ynamides and their reactions with alkynes and alkenes

Rh(I) carbenes were conveniently generated from readily available ynamides. These metal carbene intermediates could undergo metathesis with electron-rich or neutral alkynes to afford 2-oxopyrrolidines or be trapped by tethered alkenes to yield 3-azabicyclo[3.1.0]hexanes, a common skeleton in numerous bioactive pharmaceuticals. Although the scope of the former is limited, the latter reaction tolerates various substituted alkenes.

Synthesis of ynamides from formamides

N-Formyl-tosylamides can be efficiently converted to N-ethynyl-tosylamides in two steps via the corresponding dichlorovinylamides.

Stereoselective synthesis of alcohols. Part LV. Domino hydroformylation-allylboration-hydroformylation reactions to give trans-perhydropyrano[3,2-b] pyridine derivatives

N-Allyl-(E)-γ-aminoallyl boronates 8 and 18, when subjected to hydroformylation conditions, enter into a domino hydroformylation-allylboration-hydroformylation reaction cascade to generate the bicyclic N,O-heterocycles 12 and 20. On reaction of the methal

Synthesis of ynamides and ynol ethers via formamides and formates

The efficient conversion of N-formyl-tosylamides to N-ethynyl-tosylamides via the corresponding dichlorovinylamides is described. Furthermore syntheses of N-formyl-tosylamides are reported.