31236-97-2

Basic information

• Product Name: 1H-Phosphindole, 1-phenyl-, 1-oxide
• CAS NO: 31236-97-2
• Molecular Formula: C14H11OP
• Molecular Weight: 226.215
• Mol File: 31236-97-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1H-Phosphindole, 1-phenyl-, 1-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Phosphindole, 1-phenyl-, 1-oxide(31236-97-2)
• EPA Substance Registry System: 1H-Phosphindole, 1-phenyl-, 1-oxide(31236-97-2)

Safety Data

• Hazardous Substances Data: 31236-97-2(Hazardous Substances Data)

Upstream product

• 4559-70-0 Diphenylphosphine oxide 
• 74-86-2 acetylene 
• 644-97-3 Dichlorophenylphosphine 
• 2039-88-5 2-bromostyrene 
• 703-03-7 1-phenyl-2-phospholene-1-oxide 
• 52427-59-5 1-Chloro-2,3-dihydro-phosphindole 1-oxide 
• 52427-49-3 1-oxo-2,3-dihydro-1H-1λ⁵-phosphindol-1-ol 
• 2170-06-1 1-Phenyl-2-(trimethylsilyl)acetylene 
• 536-74-3 phenylacetylene 
• 65425-96-9 (Z)-β-bromo-β-(trimethylsilyl)styrene 
• 31236-98-3 1-phenyl-1-benzophosphole 
• 152554-90-0 2-(trimethylsilyl)benzo[b]phosphole P-oxide 
• 86863-35-6 trans-3a,7a-dihydrophosphindole 1-oxide 
• 31236-96-1 1-phenyl-2,3-dihydrobenzo[b]phosphole-1-oxide 

Downstream Products

• 31236-96-1 1-phenyl-2,3-dihydrobenzo[b]phosphole-1-oxide 
• 1031-13-6 5-phenyl-5H-dibenzophosphole-5-oxide 
• 1034024-38-8 2,2'-(1,4-phenylene)di(1-phenylphosphindole-1-oxide) 
• 91877-34-8 1,3,4-Triphenyl-1H-phosphindolo[3,2-c]pyrazole 4-oxide 
• 84350-85-6 2,3-dihydro-1-phenyl-2,3-dibromophosphindole oxide 
• 91877-32-6 (3aS,4S,8bR)-1,3,4-Triphenyl-3a,8b-dihydro-1H-phosphindolo[3,2-c]pyrazole 4-oxide 
• 137072-79-8 7-Oxo-7-phenyl-2,2a,7,7a-tetrahydro-1H-7λ⁵-phospha-cyclobuta[a]indene-2-carboxylic acid methyl ester 
• 31236-98-3 1-phenyl-1-benzophosphole 

Relevant articles and documents

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Synthesis of 2,3-dihydro-1-phenylbenzo[b]phosphole (1-phenylphosphindane) and its use as a mechanistic test in the asymmetric appel reaction: Decisive evidence against involvement of pseudorotation in the stereoselecting step

Racemic 2,3-dihydro-1-phenylbenzo[b]phosphole was obtained by reduction of 1-phenylbenzo[b]phosphole-1-oxide, itself derived by ring-closing metathesis of phenylstyrylvinylphosphine oxide. The title compound was then reoxidized under asymmetric Appel cond

A Versatile Synthetic Route to 1-Benzometalloles involving the First Examples of Several C-Unsubstituted Benzometalloles

The group 14 (Si, Ge, Sn), group 15 (P, As, Sb, Bi) and group 16 (S, Se, Te) (2-trimethylsilyl)-1-benzometalloles 5 have been prepared from phenylacetylene via three steps and converted into the corresponding C-unsubstituted benzometalloles 7 by detrimethylsilylation.