312932-22-2Relevant academic research and scientific papers
Synthetic, structural, chemical, and electrochemical studies of the metallatricarbadecaboranyl analogues of ferrocene, ruthenocene, and osmocene and the observation of a reversible η6-η4 tricarbadecaboranyl coordination that is analogous to the η5-η3 cyclopentadienyl ring-slippage process
Ramachandran, Bhaskar M.,Trupia, Sabrina M.,Geiger, William E.,Carroll, Patrick J.,Sneddon, Larry G.
, p. 5078 - 5090 (2002)
The synthetic, structural, chemical and electrochemical studies of the metallatricarbadecaboranyl analogues of ferrocene, ruthenocene and osmocene were presented. The electrochemical studies revealed that tricarbadecaboranyl compounds showed reversible one-electron oxidation and two successive one-electron reductions. The reduction values indicated a stabilization energy in excess of the comparative electronic effect.
