31301-27-6

Usage

Uses

Used in Coordination Chemistry:
1,10-Phenanthroline-4-carboxylic acid is used as a chelating ligand for the complexation of transition metal ions, which is crucial in coordination chemistry. Its high affinity for metal ions allows for the formation of stable complexes that are essential in various chemical and biological processes.
Used in Catalysis:
In the field of catalysis, 1,10-Phenanthroline-4-carboxylic acid is utilized as a ligand to form metal complexes that can act as catalysts. These complexes are valuable in accelerating chemical reactions, making industrial processes more efficient and sustainable.
Used in Electrochemistry:
1,10-Phenanthroline-4-carboxylic acid is employed in electrochemistry for the development of redox-active metal complexes. These complexes are useful in the design of electrochemical sensors, batteries, and other energy storage devices.
Used in Biological Studies:
In biological research, 1,10-Phenanthroline-4-carboxylic acid is used to study the interactions between metal ions and biomolecules. Its ability to form complexes with metal ions aids in understanding the role of these ions in biological systems and their potential impact on health and disease.
Used in Pharmaceutical Development:
Due to its antimicrobial and antiviral properties, 1,10-Phenanthroline-4-carboxylic acid is considered a potential candidate for the development of new pharmaceuticals. It may be used in the creation of drugs targeting various infectious diseases and conditions.
Used in Antimicrobial Applications:
1,10-Phenanthroline-4-carboxylic acid is used as an antimicrobial agent to combat bacterial infections. Its ability to form complexes with metal ions can disrupt essential metal-dependent processes in bacteria, thereby inhibiting their growth and survival.
Used in Antiviral Applications:
In antiviral applications, 1,10-Phenanthroline-4-carboxylic acid is employed to inhibit viral replication and infection. Its interaction with metal ions may interfere with viral enzymes or proteins, reducing the virus's ability to infect host cells and replicate.

Upstream product

• 31301-28-7 4-methyl-1,10-phenanthroline 
• 31301-30-1 1,10-Phenanthroline-4-carboxaldehyde 

Relevant academic research and scientific papers

A green-emitting iridium complex used for sensitizing europium ion with high quantum yield

A green-emitting iridium(III) complex Ir(dfppy)2(cbphen) (dfppy?=?2-(4′,6′-difluoro-phenyl)pyridine, cbphen?=?4-carboxylate-phenanthroline) was synthesized and fully characterized. The single crystal data confirm its Ir(C^N)2(N^N) structure with the carboxylate group on phenanthroline stretching freely which could be able to combine with europium(III) ion. The complex was reacted with EuCl3·6H2O and Eu(TTA)3·2H2O to provide bimetallic complexes. Through photophysical studies, characteristic emission from EuIIIion was obtained, and meanwhile the green emission from iridium(III) center was almost quenched completely, suggesting this iridium(III) complex is a good sensitizer for EuIIIions. It is well worth noticing that by introducing the iridium(III) complex as a chromophore, the excitation wavelength of EuIIIion has been extended to the visible range (470?nm). Besides, due to the efficient energy transfer, the quantum yield of Ir3-Eu was nearly equal to that of Eu(TTA)3·2H2O.

Cu(ii) templated formation of [: N] pseudorotaxanes (n = 2, 3, 4) using a tris-amino ether macrocyclic wheel and multidentate axles

A tris-amine and oxy-ether functionalised macrocyclic wheel (NaphMC) and various phenanthroline based multidentate axles (L1, L2 and L3) are utilised for the formation of [n]pseudorotaxanes (n = 2, 3, 4) in high yields via Cu(ii) temptation and π-π stacking interactions. The systematic development of threaded supramolecular architectures i.e. [2]pseudorotaxane {[2]CuPR(ClO4)2}, [3]pseudorotaxane {[3]CuPR(ClO4)4} and [4]pseudorotaxane {[4]CuPR(ClO4)6} from bidentate L1, linear tetradentate L2 and tripodal hexadentate L3 respectively is described. All the [n]pseudorotaxanes are well characterized by several spectroscopy and other experimental techniques such as electrospray ionization mass spectrometry (ESI-MS), isothermal titration calorimetric (ITC) study, UV/Vis, EPR, IR and elemental analysis. Moreover, the single crystal X-ray analysis of [2]pseudorotaxane confirmed the threading of L1 in the cavity of NaphMC, resulting in the formation of a penta-coordinated Cu(ii) ternary complex. ITC studies revealed the order of binding constant values for the formation of [n]pseudorotaxanes from the NaphMC-Cu(ii) complex and multidentate axles as L3 > L2 > L1. Finally, we have also shown the ability of Ni(ii) to act as a metal template in the formation of [n]pseudorotaxanes.