313053-73-5

Basic information

• Product Name: Ni(C₆F₅)[P(C₆H₅)(CH₃)2][S₂CN(C₂H₅)2]
• CAS NO: 313053-73-5
• Molecular Weight: 512.17
• Mol File: 313053-73-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ni(C₆F₅)[P(C₆H₅)(CH₃)2][S₂CN(C₂H₅)2](CAS DataBase Reference)
• NIST Chemistry Reference: Ni(C₆F₅)[P(C₆H₅)(CH₃)2][S₂CN(C₂H₅)2](313053-73-5)
• EPA Substance Registry System: Ni(C₆F₅)[P(C₆H₅)(CH₃)2][S₂CN(C₂H₅)2](313053-73-5)

Safety Data

• Hazardous Substances Data: 313053-73-5(Hazardous Substances Data)

Upstream product

• 313053-84-8 Ni(C₆F₅)Cl[P(C₆H₅)(CH₃)2]2 
• 3699-30-7 potassium diethyldithiocarbamate 

Relevant articles and documents

Organometallic nickel(II) complexes containing thiolate and dithiocarbamate ligands

The mono(pentafluorophenyl)nickel(II) complexes [Ni(C6F5)ClL2] (L = PPhMe2, PPh2Me; L2 = dppe) react with KSR (R = Ph, C6H4Me-p, C6H4OMe-p, C6H4Cl-p, C6H3Cl2-2,6, C6H4NO2-p) at room temperature in acetone/dichloromethane to give the mononuclear thiolate complexes [Ni(C6F5)(SR)L2]. The binuclear μ-thiolate complex [{Ni(C6F5)(PPhMe2)}2(μ-SC6H4NO2-p)2] is obtained by reaction of KSC6H4NO2-p with the same chloro complex in refluxing dichloromethane. A single-crystal X-ray diffraction study of [Ni(C6F5)(SC6H4NO2-p)(PPhMe2)2] and [{Ni2(C6F5)2(PPhMe2)2(μ-SC6H4NO2-p)2] has established the mononuclear and binuclear nature of the complexes. The dithiocarbamatenickel complexes [Ni(C6F5)(S2CNR2)L] (L = PPhMe2, PPh2Me, PEt3; R = Et, iPr; R2 = C5H10, C4H8O) have been prepared by reaction of [Ni(C6F5)ClL2] (L = PPhMe2, PPh2Me, PEt3) with the alkali metal salt of the corresponding dithioacid. A single-crystal X-ray diffraction study of [Ni(C6F5)(S2CNiP2)(PPhMe2)] has established the mononuclear nature of the complex, and the geometry around each Ni atom as that of a tetrahedrally distorted square-planar geometry. Analytical (C, H, N), spectroscopic (IR, 1H, and 19F NMR), and mass spectrometry (FAB) data have been used for structural assignments.