313333-70-9

Upstream product

• 79826-88-3 [ethyl-(14RS)-(14-cyano-12,13,14,17-tetrahydro-2,3,8,13,13,14-heptamethyl-15H-tripyrrin-1-carboxylato)]nickel(II) 
• 6018-89-9 nickel(II) acetate tetrahydrate 
• 262611-68-7 Benzyl-(6-formyl-3,5-dihydro-1H-thieno[3,4-c]pyrrol-4-carboxylat)-2,2-dioxid 
• 262611-69-8 benzyl 20-cyano-1,3,18,19,20,24-hexahydro-8,9,13,14,19,19,20-heptamethyl-22H-thieno[3,4-b]biline-4-carboxylate 2,2-dioxide 

Relevant academic research and scientific papers

Simple synthesis of a chlorin - fullerene dyad with a novel ring-closure reaction

To model the photosynthetic reaction center, the chlorin- fullerene dyad 1 was synthesized in a one-pot reaction from a linear tetrapyrrole and C60. It is the first dyad of this type which contains a fullerene and a chlorin unit, the chromophore of naturally occurring photosynthetic systems.

Synthesis of sulfolenobilins and their cyclization directed to chlorinatozinc-fullerene dyads

A novel chlorinatozinc-fullerene dyad 18 was synthesized to model the photosynthetic reaction center. The synthetic key step for the formation of the dyad 18 is an unusual one-pot reaction of the (sulfolenobilinato)-nickel rac-16a,b with concomitant gener