313352-89-5Relevant academic research and scientific papers
A Simple Route to N-Arylated 2-Aminothiophenes as a New Class of Amorphous Glass Forming Molecules
Hartmann, Horst,Gerstner, Peter,Rohde, Dirk
, p. 1673 - 1675 (2007/10/03)
(matrix presented) By thermal decarboxylation of N-arylated 2-aminothiophene-5-cacrboxylates, a versatile, heavy-metal free method for preparing the title compounds as new class of highly reactive and easily oxidable, amorphous glass forming molecules has been elaborated.
A simple route to N,N-dialkyl derivatives of 2-amino-5-thiophenecarboxylates
Heyde, Cornelia,Zug, Ines,Hartmann, Horst
, p. 3273 - 3278 (2007/10/03)
Starting from acetamides 4 and using three different routes - via thioacetamides 5, 3-amino-thioacrylamides 7, or 3-chloropropeniminium salts 6 - a series of new N,N-dialkyl derivatives of 2-amino-5-thiophenecarboxylates 10 has been prepared and analytically and spectroscopically characterized.
