31351-00-5

Basic information

• Product Name: 2,6-Cyclooctadien-1-one, (Z,Z)-
• CAS NO: 31351-00-5
• Molecular Formula: C8H10O
• Molecular Weight: 122.167
• Mol File: 31351-00-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2,6-Cyclooctadien-1-one, (Z,Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-Cyclooctadien-1-one, (Z,Z)-(31351-00-5)
• EPA Substance Registry System: 2,6-Cyclooctadien-1-one, (Z,Z)-(31351-00-5)

Safety Data

• Hazardous Substances Data: 31351-00-5(Hazardous Substances Data)

Upstream product

• 1552-12-1 1,5-cis,cis-cyclooctadiene 

Downstream Products

• 97877-72-0 9-isobutyl-9-azabicyclo<3.3.1>nonan-3-one 
• 2291-58-9 9-benzyl-9-azabicyclo[3.3.1]nonan-3-one 
• 68344-46-7 1,5-Cyclooctadien-3-in 
• 80326-64-3 4-Phenyl-2,4,6-triazatricyclo<5.4.2.0^2,6>tridec-12-en-9-in-3,5-dion 
• 80339-91-9 1,3-Cyclooctadien-6-in 
• 68344-47-8 7,8-Dihydro-1,2,3,4-tetraphenylbenzocycloocten 

Relevant articles and documents

Iron-catalyzed epoxidation of aromatic olefins and 1,3-dienes

The combination of iron(III) chloride, pyridine-2,6-dicarboxylic acid and formamidine ligands allows for the epoxidation of styrenes and conjugated dienes in excellent chemoselectivity and yields.

LIQUID PHASE OXIDATION OF CYCLIC POLYOLEFINS WITH MOLECULAR OXYGEN. PART II. CIS,CIS-1,5-CYCLOOCTADIENE AUTOOXIDATION

The autooxidation of 1,5-cyclooctadiene has been studied.Cyclooctadiene easily undergoes oxidation by molecular oxygen.Depending on the reaction procedure and the degree of conversion, polymeric or monomeric oxidated products are the dominating products with the preservation of eight-membered ring.The content of 1,2-epoxycyclooctene-5 in the product may exceed 50percent.The reaction was found to be of a free-radical character.An initiation and propagation scheme of the autooxidation is proposed.