313697-17-5Relevant academic research and scientific papers
Copper- and Cobalt-Catalyzed Syntheses of Thiophene-Based Tertiary Amines
Bouarfa, Salima,Gra?l, Simon,Ivanova, Maria,Langlais, Timothy,Bentabed-Ababsa, Ghenia,Lassagne, Frédéric,Erb, William,Roisnel, Thierry,Dorcet, Vincent,Knochel, Paul,Mongin, Florence
, p. 3244 - 3258 (2019)
Thienylzinc halides and related compounds prepared by deprotonation followed by transmetalation were used in copper-catalyzed amination using N-benzoyloxy secondary amines. By extending the reaction to 1,5-naphthyridine, it was showed that the competitive dimer formation observed in the case of thiophenes was linked with the low stability of some thienylamines rather than homocoupling. Interestingly, thienylzinc halides and related compounds prepared by transmetalation of thienylmagnesium halides, either prepared from their bromo-precursors or generated by deprotometalation, were satisfactorily employed in cobalt-catalyzed aminations. Finally, aminothiophenes were involved in copper-catalyzed mono- and di-N-arylations, affording differently substituted di- and triphenylamines.
Palladium catalysed amination of electron deficient halothiophenes
Luker, Tim J.,Beaton, Haydn G.,Whiting, Mat,Mete, Antonio,Cheshire, David R.
, p. 7731 - 7735 (2000)
A range of functionalised aminothiophenes has been prepared via palladium-catalysed aminations. The reaction proceeds in high yield when the halide is conjugated to an electron-withdrawing group and is suitable for a wide variety of amines. (C) 2000 Elsevier Science Ltd.
LIGHT-EMITTING MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE, ORGANIC ELECTROLUMINESCENT DEVICE USING SAME, AND MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE
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Paragraph 0252-0257; 0259, (2021/01/28)
Disclosed are a fused compound having excellent emission wavelength control and luminous efficiency, a method for manufacturing the same, and an organic electronic device including the fused compound. Symmetric, asymmetric, and planar structures of the pr
Ullmann-type: N-arylation of anilines with alkyl(aryl)sulfonium salts
Tian, Ze-Yu,Zhang, Cheng-Pan
supporting information, p. 11936 - 11939 (2019/10/11)
A palladium/copper-cocatalyzed Ullmann-type N-arylation of anilines using alkyl(aryl)sulfonium triflates as arylation reagents has been accomplished. The reaction enabled Caryl-S bond cleavage over Calkyl-S bond breakage of alkyl(aryl)sulfoniums by Pd(P(tBu)3)2/CuI and gave the corresponding N-arylated products in good to high yields. It was also significant that the reactions of aniline with asymmetric butyl(mesityl)(aryl)sulfonium triflates showed excellent selectivity, in which the aryl groups other than the bulky and electron-rich mesityl moieties were transformed.
An advantageous synthesis of new indazolone and pyrazolone derivatives
Correa, Arkaitz,Tellitu, Imanol,Domínguez, Esther,SanMartin, Raul
, p. 11100 - 11105 (2007/10/03)
The synthesis of new indazolone and pyrazolone derivatives starting from methyl anthranilate type substrates is presented. This general approach constitutes a novel and advantageous alternative for the synthesis of the target heterocycles, which implies the use of the environmentally friendly oxidizer PIFA. The synthetic design includes the oxidation of N-arylamides by the hypervalent iodine reagent to the corresponding N-acylnitrenium ions, which can be intramolecularly trapped by an amine moiety to furnish the title compounds by formation of a new N-N single bond.
